My of my favourite pedals on my pedalboard at the moment is the Electro Harmonix Micro Pog, this little blighter is a fantastic sonic addition to any set-up.
Basically it's polyphonic, got 3 very user-friendly knobs, dry signal (input signal) volume, sub octave volume (-1 octave), octave up volume (+1 octave) the octave sound it creates reacts fast and sticks closely along side your original guitar signal and you can play more than one note through this unit at a time tracing your notes and chords almost seamlessly. It's great for electric organ sounds, or can make a 6 string guitar sound like a bass or 12 string, you can get great Jack White tones when distortion, overdrive and basically anything over 11 is applied.
Time to fire up my amp methinks.
image Sound Unlimited